Defect Induced Polarization Loss in Multi-Shelled Spinel Hollow Spheres for Electromagnetic Wave Absorption Application

Significance 

The development of efficient electromagnetic wave absorbers needed to reduce interference has gained significant research attention in recent years. Cobalt-based spinel structure metal oxides have been identified as favorite candidates for this application. Co-based spinel MCo2O4 electromagnetic wave absorbers have been prepared recently and show potential electromagnetic wave absorption properties. Despite these promising results, the high density of MCo2O4 based absorbers still hamper their application. However, more research is required on these absorbers and their electromagnetic wave attenuation.

In light of these insufficiencies, a design of specific morphology to lower the density of MCo2O4 based EM wave absorbers is highly desired. Developing hollow-structured materials is seen as a sure path to solving this important research issue. This is why multi-shelled hollow spheres have attracted much attention due to their lightweight structure, shell porosity, intershell spacing, and controllable shell numbers and thickness. The multi-shelled hollow spheres micro/nanostructure promotes EM wave absorption by: the multiple shells lead to numerous reflections when the incident electromagnetic wave propagates through two adjacent shells, secondly, the generated shell-air-shell interfaces boost interfacial polarization, thirdly, multiple cavities in this structure help circumvent the MCo2O4 high-density issue.

Unfortunately, only a handful of studies have focused on multi-shelled hollow spheres-based EM absorbers. Besides morphology regulation, it would also be essential to investigate the quantitative relationship and desirable dissipation mechanism in dielectric loss materials. Previous studies have paid much attention to the design of unique structures to distinguish the dominant loss mechanism. Still, an investigation on defect engineering and its induced polarization loss dominant electromagnetic wave absorbers hasn’t received much attention. And this is why it would be necessary first to clarify the EM wave absorbing mechanism primarily caused by defect-induced polarization loss.

Inspired by this thought, researchers Dr. Ming Qin, Dr. Limin Zhang, Dr. Xiaoru Zhao, and Professor Hongjing Wu from the Northwestern Polytechnical University in China proposed a versatile route for the preparation of multi-shelled MCo2O4 based hollow spheres structured materials. The authors demonstrated for the first time the defect-induced dielectric loss dominant mechanism as a result of multi-shelled spinel hollow spheres. Their research work is published in the journal Advanced Science.

The authors rapidly attained samples with the same tripled-shelled structure through identical synthetic routes. They first selected NiCo2O4-based materials as representatives and modified their defects in crystal and oxygen vacancy. The authors then extended this principle to serial Co-based multi-shelled hollow sphere materials under ideal defect site engineering temperature.

The authors observed that various bivalent metals ions had a different affinity for carbon spheres than Co ions, which led to the formation of multi-shelled hollow spheres with varied crystalline phases. By investigating the composition, conductivity, and defect sites in ferrites, the authors observed that electromagnetic dissipation from conduction loss, interfacial polarization, and dipolar polarization didn’t play a significant role compared to defect-induced polarization loss. Using NiO/NiCo2O4 composites as representatives, the researchers observed two defects: oxygen vacancy and crystal structure in the spinel structure. Crystal defect contribution was more profound; therefore, electromagnetic wave dissipation characteristics followed its variance tendency.

In a bid to validate their discovery, the authors analyzed the electromagnetic wave absorption performance of serial Co-based multi-shelled hollow sphere materials. By analyzing the characterization results, they found that NiO/NiCo2O4 composites had the highest defect sites in the spinel structure, therefore reporting the best electromagnetic wave absorption performance.

When it came to the peculiar multi-shelled hollow sphere’s structure, the researchers demonstrated the defect-induced dielectric loss dominant mechanism for the first time. They also observed that electron spin resonance signal measurement proportionally matched the EM wave absorption capacities of the measured materials. This discovery could go a long way in opening an avenue to select superior EM wave absorbers rapidly. Ultimately, the findings of this study will inspire the fabrication of high-performance and lightweight ferrite EM wave absorbers by defect engineering.

Defect Induced Polarization Loss in Multi-Shelled Spinel Hollow Spheres for Electromagnetic Wave Absorption Application - Medicine Innovates
Multi-shelled MCo2O4 hollow sphere ferrites were synthesized via a facile hydrothermal method realized by competitive adsorption mechanism. It revealed that defect in spinel structure and it induced loss mechanism plays dominate role over other loss mechanisms. In consequence, electromagnetic wave absorption capacities of serial ferrites could be tailored through defect engineering. The strong absorption intensity and lightweight feature of multi-shelled hollow sphere ferrites will ensure them attractive electromagnetic wave absorbing materials, especially for the potential application of stealth fighter in the future.

About the author

Dr. Ming Min was born in 1993. He received her B.S. degree with a major in applied chemistry in 2015 from China University of Geosciences (Wuhan) and M.S. degree in chemistry from China University of Geosciences (Wuhan) in 2018. Then he joined Prof. Hongjing Wu’s group. Currently, he is working towards Ph.D. degree in physics at NWPU. His current research interest is synthesis and characterization of metal oxides, and design and application of metal oxides-based multifunctional composites.

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About the author

Prof. Hongjing Wu was born in 1984. He received B.S. degree from China University of Geosciences (Wuhan) with a major in applied chemistry in 2007 and obtained a M.S. degree in chemistry from China University of Geosciences (Wuhan) in 2010. Since September 2010, he has been studying for a Ph.D. degree in materials physics and chemistry at Northwestern Polytechnical University (NWPU). From November 2012 to November 2013, he visited and exchanged at the Institute of Nanostructured Materials of the National Research Council (CNR-ISMN, Italy). His current research interest includes theoretical design, preparation, synthesis, physical and chemical characterization and stealth application of electromagnetic wave absorbing (stealth) materials. He has published more than 100 academic papers (see https://scholar.google.com.hk/citations?user=3OPzWSAAAAAJ&hl=zh-CN&oi=ao) in scientific journals (including more than 20 ESI highly cited papers) and 5 book chapters. The academic papers have been cited more than 4,600 times, and his Google H factor up to 38. Currently, he was served as the editor of Journal of Materials Science: Materials in Electronics, and guest editor of Catalysts, Journal of Nanoscience and Nanotechnology, Current Nanoscience, etc.

Reference

Ming Qin, Limin Zhang, Xiaoru Zhao, and Hongjing Wu. Defect Induced Polarization Loss in Multi-Shelled Spinel Hollow Spheres for Electromagnetic Wave Absorption Application. Advanced Science 2021, 8, 2004640.

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